In the “Send mail as” section, click Add another email address.
Enter your name and the address you want to send from.
Since Alias email was set to *, you can specify <anything>@<your_domain>. For each mailbox that you want to add (such as those specified in RFC 2142), you will need to repeat the Add another email address process.
Keep Treat as an alias checked, as there is no other mail system that you can access emails to your domain. To verify your use case, see: Should I uncheck “Treat as an alias” in Gmail?.
Click Next Step
Set SMTP Server to smtp.gmail.com, leaving Port set to 587
Set Username to your Google ID, i.e. the <id> portion of <id>@gmail.com
Set Password to the App Password you generated in the previous section
Click Add Account
Verify the account by clicking the link sent to your Gmail